The bulk polymerization of vinyl chloride initiated by AIBN at temperature levels of 30°, 50°, and 70°C has been studied. Molecular weight averages and distribution (MWD) were measured by gel permeation chromatography. A model has been proposed which accurately predicts conversion to high levels and MWD. Molecular weight measurements show that transfer to monomer plays the important role in controlling molecular weight averages. Disproportionation is probably the dominant mode of termination.
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Abdel‐Alim et al. (1972) studied this question.
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