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Synthetic chemistry report demonstrates diastereoselective electrophilic fluorination of chlorolactone, suggesting an efficient route to fluorinated ribose analogs.
A novel and efficient route for the preparation of (2S)-2-chloro-2-fluorolactone 29 is described. This approach takes advantage of a highly efficient diastereoselective electrophilic fluorination reaction (94% yield; >50:1 dr).
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Schutter et al. (2017) studied this question.
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