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A linear bis(phosphine) palladium(0) complex with the bulky aryl substituent, tris(2,2″,6,6″-tetramethyl-m-terphenyl-5′-yl (Tmtp), was found to crystallize as a spontaneously resolved homochiral clathrate with toluene molecules.
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Matsumoto et al. (2002) studied this question.
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