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The reaction of (CF3)2CC(F)CF2CF3 or CF3CFCF2 with Ru(dmpe)2H2 affords the bifluoride fluoride complex cis-Ru(dmpe)2F(F⋯HF), whereas reaction with Ru(dcpe)2H2 yields the cation [Ru(dcpe)2H]+ with [(CF3)2CC(O)CF2CF3] − as the anion.
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Kirkham et al. (2001) studied this question.
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