Bye bye multiple-bond rule: Recent successes in silicon chemistry are the silicon-containing compounds 1, which has a SiSi triple bond, and the [(Me5C5)Si]+ ion 2, which is a stable derivative of the [HSi]+ ion. Both species are also notable from a bond-theory point of view and can be regarded as valuable starting materials for synthetic organosilicon chemistry.
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Manfred Weidenbruch (2004) studied this question.
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