Dipolar-glass-like relaxor ferroelectric behaviour in the 0.5BaTiO3-0.5Bi(Mg1/2Ti1/2)O3 electroceramic

In this study, the dielectric and ferroelectric switching behaviour of 0.5BaTiO3-0.5Bi(Mg1/2Ti1/2)O3 (BT-BMT) ceramics are investigated. The BT-BMT ceramic exhibits a typical dipolar-glass-like, dielectric polarisation relaxation. This is attributed to the 15 distinct possible local A4B2 configurations around the O ions and the effect this unavoidable local compositional variability has on the dipole relaxation behaviour of inherent 1-D ⟨111⟩ dipole chains, arising from correlated off-centre displacements of Bi3+ and Ti4+ ions along local ⟨111⟩ directions. On the other hand, switchable polarisation under strong applied electric fields is observed on different length scales accompanied by the appearance of strong polarisation relaxation, as observed via time-delayed piezoresponse hysteresis loop measurements. These experimental results demonstrate that this BT-BMT ceramic is relaxor ferroelectric in nature, although it exhibits dipolar-glass-like dielectric relaxation behaviour.