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The excited-state dynamics of silylene-diphenylene copolyemers, –[(SiMe2)m–(C6H4)2]n–, m = 1, 2, 3, 4, and 6, was studied by picosecond time-resolved emission anisotropy. The emission depolarization within 100 ps suggested the effective energy migration along the σ–π conjugated silylene-diphenylene chain.
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Fang et al. (1996) studied this question.
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