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Activity coefficients at infinite dilution of alkanes, alkenes, and alkylbenzenes as well as of the linear and branched C 1 −C 6 alcohols, esters, and aldehydes in the ionic liquids 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide have been determined by gas chromatography using the ionic liquids as stationary phase. The measurements were carried out at different temperatures between 301 K and 396 K. From the temperature dependence of the limiting activity coefficients, partial molar excess enthalpies at infinite dilution of the solutes in the ionic liquids have been derived.
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Heintz et al. (2006) studied this question.
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