Nickel−Copper Oxygen Carriers To Reach Zero CO and H2 Emissions in Chemical-Looping Combustion

Ni-based oxygen carriers allow working at high temperatures (900−1100 °C) in a chemical-looping combustion (CLC) process with full CH 4 conversion, although thermodynamic restrictions result in the presence of CO and H 2 in the gas outlet of the fuel reactor. On the other hand, Cu-based oxygen carriers allow complete fuel combustion to CO 2 and H 2 O, but the operating temperature is limited due to the low melting point of the metallic Cu. The objective of this research was to analyze the behavior of several Ni−Cu oxygen carriers to reduce or avoid CO and H 2 emissions during a CLC process working at high temperatures. Commercial γ-Al 2 O 3 and α-Al 2 O 3 were used as support to prepare by dry impregnation different oxygen carriers based on nickel and copper. The reactivity of these oxygen carriers was determined in a thermogravimetric analyzer (TGA). The effect of the mixture of NiO and CuO on the CO and H 2 generation was analyzed in a fixed bed reactor, and the gas product distribution during reduction/oxidation reactions was studied in a batch fluidized bed reactor working with CH 4 as fuel and diluted air for oxidation. The fluidization behavior of the oxygen carriers with respect to the attrition and agglomeration processes was also analyzed during the multicycle batch fluidized bed tests. The presence of CuO in the Ni−Cu oxygen carriers allows the full conversion of CH 4 to CO 2 and H 2 O in the batch fluidized bed reactor during the initial part of the reduction time, and this time depended on the CuO content of the oxygen carrier. TGA and X-ray diffraction studies indicated that CuO is used for the reduction reaction before NiO. In addition, it was observed that the presence of NiO stabilized the CuO and allowed working at 950 °C with Ni−Cu oxygen carriers with a high metal oxide utilization.