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Electrically conductive semi‐IPNs based on polyaniline and crosslinked polyvinylacetate were prepared. Polyaniline successfully percolated through the crosslinked PVAc networks and the resulting semi‐IPNs show a continuous network morphology. The conductivity of the semi‐IPN increases with increasing content of polyaniline and increasing acidity used during the polymerization of the polyaniline. The conductivity of the semi‐IPN is 0.13 S/cm, with the highest polyaniline content of 19.3 wt %. The depression of polyaniline with temperature change is smallest followed by the depression of semi‐IPN of the polyaniline/crosslinked polyvinylacetate, which is considerably smaller than the depression of crosslinked polyvinylacetate.
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Ma et al. (2002) studied this question.
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