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Asymmetric Diels-Alder reaction between cyclopentadiene and alkyl and cycloalkyl acrylates in the presence of new chiral catalysts, BBr 3 ·MentOEt, AlCl 2 OMent, BBr 2 OMent, and BBr(OMent) 2 , was studied. Optically active bicyclo[2.2.1]hept-2-ene-5-carboxylates were synthesized. The influence of the reaction conditions on the total and optical yields and on the stereoselectivity of the adducts synthesized was examined.
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E. G. Mamedov (2006) studied this question.
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