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April 1, 2009Physics and Chemistry of LiquidsOpen Access

Semi-empirical relation between freezing point and critical point properties of a wide variety of molecular liquids

M. Yu. Gorbachev

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Abstract

Based on experimental data for some 28 freezing liquids, we define a semi-empirical relation connecting surface tension and molar volume with the molar critical volume. It is shown that the semi-empirical equation deduced by means of this relation allows one to calculate the given critical property for various molecular liquids with high accuracy.

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M. Yu. Gorbachev (2009) studied this question.

synapsesocial.com/papers/6aa6bf08041e43fea73a82e8 https://doi.org/10.1080/00319100701810222

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