This paper presents some current progress on biodegradable materials that are based on plasticized starch (PLS). To improve the hydrophobic character of the material for packaging applications, for example, a recent and promising development based on a PLS–biopolyester (e.g. polycaprolactone) blend with plasma-coated SiOx is presented. PLS–biopolyester blends can show, under certain processing conditions, a pseudo-multilayer structure with a polyester skin that allows good adhesion of SiOx deposits. XPS and FTIR-ATR determinations are used to assess the outer surface.
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Bélard et al. (2005) studied this question.
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