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The reaction of trans -[RuNO(NH 3 ) 4 (OH)]Cl 2 with nitric acid has been studied. Reaction products have been identified by IR spectroscopy, NMR, mass spectrometry, powder and single-crystal X-ray diffraction, and chemical analysis. Synthesis methods have been developed for amminenitrosoruthenium complexes containing outer-sphere and coordinated nitrate ions: trans -[RuNO(NH 3 ) 4 (H 2 O)](NO 3 ) 3 ( I ), trans -[RuNO(NH 3 ) 4 (NO 3 )](NO 3 ) 2 ( II ), and fac -[RuNO(NH 3 ) 2 (NO 3 ) 3 ] ( III ). Complex II has two polymorphs: monoclinic and tetragonal. The latter has been studied by X-ray crystallography.
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Kabin et al. (2012) studied this question.
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