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LiSn crystallizes monoclinic: a = 5.17 ± 0.02 Å; b = 7.74 ± 0.02 Å; c = 3.18 ± 0.02 Å; γ = 104.5° ± 0.3°, space group: P 2/m - C2h 1. LiSn is not isotypic with LiGe and LiPb, but there are many structural relations to LiPb.
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Müller et al. (1973) studied this question.
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