A new method of forming TiO2 gate insulators is proposed. It was found that ultrathin TiN deposition on ultrathin SiO2 and low-temperature thermal oxidation resulted in smaller TiO2 grains surrounded by amorphous boundaries. The gate leakage current was effectively reduced by applying ultrathin TiO2/SiO2 stacked insulators to metal-oxide-semiconductor (MOS) capacitors and Damascene gate metal-oxide-semiconductor-field-effect-transistors (MOSFETs) with good characteristics were successfully fabricated.
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Nakajima et al. (2000) studied this question.
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