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September 17, 2026ACS OmegaOpen Access

Balancing Color Stability and Mechanical Performance in Sole Leather: A Sustainable Materials Approach Using Vegetable Tannin Formulations

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Authors

EBEmre BasaranAYAli YorgancıoğluNENilay Örk Efendioğlu

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Overview

Material evaluation reveals optimized mimosa, quebracho, and chestnut tannin blends balance color and strength in sole leather, highlighting sustainable chromium-free tanning alternatives.

Key Points

  • To systematically evaluate the effects of single, binary, and ternary vegetable tannin combinations on the mechanical strength, structural integrity, and color stability of sole leathers.
  • Applied mimosa, quebracho, and chestnut tannins as single (40%), binary (mimosa–quebracho at varying ratios), and ternary formulations (mimosa–quebracho with a fixed 5% chestnut) to sole leather.
  • Assessed tannin fixation, fiber organization, and structural preservation using Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM).
  • Evaluated mechanical strength (tensile, tear, softness, hardness), hydrothermal stability via shrinkage temperature, and color stability using UV-aging tests (measuring ΔE).
  • Quebracho-based leathers yielded higher tensile and tear strength, while mimosa imparted lighter shades and greater softness; binary formulations of 15% mimosa with 25% quebracho and 25% mimosa with 15% quebracho balanced color homogeneity with mechanical performance.
  • Ternary systems with 5% chestnut tannin enhanced leather shrinkage temperature and overall mechanical stability while slightly altering color.
  • UV-aging tests showed mimosa-rich leathers experienced greater total color change (ΔE), whereas quebracho and chestnut improved resistance to UV degradation.

Cite This Study

Basaran et al. (2026) studied this question.

synapsesocial.com/papers/6aabb69c5f706d05830e5272https://doi.org/10.1021/acsomega.5c10534
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