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September 17, 2026International Journal of Food PropertiesOpen Access

Thermal degradation and rheological properties of different hydrocolloid gums

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Authors

SHShahzad HussainAAAbdulrahman AlahmedAMAbdellatif A. Mohamed

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Overview

Comparative analysis demonstrates divergent thermal stability and viscoelastic profiles across four hydrocolloid gums, highlighting structural determinants for food and industrial processing.

Key Points

  • To comparatively evaluate the thermal degradation kinetics and rheological behaviors of xanthan, guar, fenugreek, and Arabic gums to establish structure–property relationships.
  • Evaluated xanthan, guar, fenugreek, and Arabic gums using thermogravimetric analysis alongside Flynn–Wall–Ozawa and Kissinger kinetic models to determine activation energy.
  • Calculated initial polymer decomposition temperature and thermal heat resistance index to capture distinct dimensions of thermal stability.
  • Conducted oscillatory rheology to measure the storage modulus and loss modulus across the hydrocolloid gums.
  • Kissinger activation energies were 168.6 kJ/mol (xanthan), 145.6 kJ/mol (guar), 104.7 kJ/mol (fenugreek), and 157.1 kJ/mol (Arabic), whereas Flynn–Wall–Ozawa models yielded 194.96 kJ/mol (R² = 0.89), 151.88 kJ/mol, 152.56 kJ/mol, and 150.23 kJ/mol, respectively.
  • Arabic gum exhibited the highest overall thermal heat resistance index but recorded the lowest initial polymer decomposition temperature among all four gums.
  • Elastic storage modulus followed the order of xanthan > guar > fenugreek > Arabic gum, while viscous loss modulus ranked as guar > xanthan > fenugreek > Arabic gum.

Cite This Study

Hussain et al. (2026) studied this question.

synapsesocial.com/papers/6aabb74e5f706d05830e6352https://doi.org/10.1080/10942912.2026.2733736
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