We have established a simple method for the preparation of crystalline Fischer’s glucopyranosyl isocyanate 1. NMR spectroscopic analysis of 1 allowed the unambiguous determination of the stereochemistry at the anomeric position. Synthetic applications of glucopyranosyl isocyanate 1 were examined by its reactions with amines and alcohols to furnish a wide variety of neoglycoconjugates. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
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Ichikawa et al. (2004) studied this question.
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