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The photoluminescence quantum efficiency as well as the processing properties of a series of brightly luminescent Cu(I)-metallopolymers strongly depended on the chosen synthetic approach. A monomeric, substituted styrenic complex features a photoluminescence quantum efficiency (PLQY) of only 4%, while its metallopolymeric thin film is over one order of magnitude more efficient.
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Volz et al. (2013) studied this question.
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