Experimental study demonstrates semiconducting behavior in a TMTSF-dysprosium molecular crystal, indicating potential for multifunctional materials.
A new molecular conductor of (TMTSF)5[Dy(NCS)4(NO3)2]CHCl3 was prepared using the electrochemical oxidation method. The complex crystallizes in the Cmc21 (36) space group, where the partially-oxidized TMTSF molecules form a 1D (one-dimensional) column structure. The crystal shows a semiconducting behavior with a room temperature conductivity of 0.2 S·cm−1 and an activation energy of 34 meV at ambient pressure.
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Wan et al. (2023) studied this question.
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