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The standard Davydov Hamiltonian can be partially diagonalized using a method due to Eremko, Gaididei, and Vakhnenko. The complete Hamiltonian in this partially diagonalized form, however, includes a term omitted by these authors. Using this term in a first-order perturbation theory calculation results in an estimate of the lifetime of a Davydov soliton at finite temperatures. The lifetime at 300 K is on the order of 10^-12 s for parameters appropriate for the {α}-helical protein molecule. This is too short to be useful in biological processes.
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Cottingham et al. (1989) studied this question.
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