Activation energy for diamond growth from the carbon–hydrogen gas system at low substrate temperatures

The growth kinetics of diamond films deposited at low substrate temperatures (600–400 °C) from the carbon–hydrogen gas system have been studied. When the substrate temperature alone was varied, independently of all other process parameters in the microwave plasma reactor, an activation energy in the order of 7 kcal/mol was observed. This value did not change with different carbon concentrations in hydrogen. It is supposed that growth kinetics in this temperature range are controlled by a single chemical reaction, probably the abstraction of surface bonded hydrogen by gas phase atomic hydrogen.