Preparation of Microporous Polypropylene/Titanium Dioxide Composite Membranes with Enhanced Electrolyte Uptake Capability via Melt Extruding and Stretching

In this work, a blending strategy based on compounding the hydrophilic titanium dioxide (TiO₂) particles with the host polypropylene (PP) pellets, followed by the common membrane manufacture process of melt extruding/annealing/stretching, was used to improve the polarity and thus electrolyte uptake capability of the PP-based microporous membranes. The influence of the TiO₂ particles on the crystallinity and crystalline orientation of the PP matrix was studied using differential scanning calorimetry (DSC), X-ray diffraction (XRD), and infrared dichroic methods. The results showed that the TiO₂ incorporation has little influence on the oriented lamellar structure of the PP-based composite films. Investigations of the deformation behavior indicated that both the lamellar separation and interfacial debonding occurred when the PP/TiO₂ composite films were subjected to uniaxial tensile stress. The scanning electron microscopy (SEM) observations verified that two forms of micropores were generated in the stretched PP/TiO₂ composite membranes. Compared to the virgin PP membrane, the PP/TiO₂ composite membranes especially at high TiO₂ loadings showed significant improvements in terms of water vapor permeability, polarity, and electrolyte uptake capability. The electrolyte uptake of the PP/TiO₂ composite membrane with 40 wt % TiO₂ was 104%, which had almost doubled compared with that of the virgin PP membrane.