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An organic π-donor TMET-STF (trimethylene(ethylenedithio)diselenadithiafulvalene) was synthesized using a method via a titanocene complex. The cation radical salt (TMET-STF)2ClO4 is metallic down to 22 K and shows an upturn of resistivity. Crystal structure analysis and band calculation indicate that this system contains two types of donor columns; the one is one-dimensional and the other is two-dimensional.
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Okano et al. (1993) studied this question.
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