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Volatile, thermally robust 1,1-dimethylhydrazidogallane, [H2GaN(H)NMe2]21 has been synthesized from the reaction of H3Ga(NMe3) with H2NNMe2, whereas reaction of compound 1 with an excess of H2NNMe2 at elevated temperature afforded a gallium hydrazide derivative, Ga4[N(H)NMe2]8(NNMe2)2 2, which possessed a novel structure of two Ga2N2 rings bridged by NNMe2 groups.
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Luo et al. (2000) studied this question.
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