The manganese oxo-cluster, [Mn 12 O 12 (O 2 CMe) 16 (H 2 O) 4 ]·2(HO 2 CMe)·4(H 2 O), (Mn-12), has been the subject of intense interest for its novel magnetic properties. Although it is a model system for nanoscale magnetic data storage, no methods for forming films or attaching the cluster to surfaces have been reported. Here we demonstrate a simple approach using functionalized self-assembled monolayers and short-chain polyelectrolytes to make monolayer and nanometer-scale multilayer films of Mn-12.
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Steckel et al. (2004) studied this question.
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