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The formation of clogging materials in an immersednozzle during the continuous casting of Ti-stabilized stainless steel was studied by plant and laboratory expe!iments.The major materials deposited were globular Ti oxide as curved chain and Al.O. as large, black agglomerates.On the contrary, TiN and Al.O.were observed in the steel in the tundish, and Ti oxide was scarcely found.The curved chain of globular Ti oxide could only have been formed by reoxidation after nitrogen absorption in the laboratory experiments.The formation mechanism for Ti oxide from TiN decomposition is proposed for the clogging behaviour of Ti-stabilized stainless stee[.
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Gao et al. (1993) studied this question.
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