A new apparatus is described in which the solubility of deuterium sulfide in deuterium oxide and of hydrogen sulfide in water have been determined with 0.1 % accuracy between 0 and 50 °C. Solubility equations are derived and the solubility standard thermodynamic function changes, together with their standard errors, are tabluated. Equal solubilities would occur at −1 °C. The solubility of hydrogen sulfide in water is greater than for deuterium sulfide in deuterium oxide, the solubility difference increases to a maximum at 40 °C and thence decreases at higher temperatures.
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Clarke et al. (1971) studied this question.
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