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The tetrahedral gallium(I) compound Ga4[C(SiMe3)3]4 1 reacted with white phosphorus by the threefold insertion of its monovalent gallium atoms into P–P bonds of the P4 tetrahedron with formation of a novel P4(GaR)3 cage possessing a structure similar to P4S3.
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Uhl et al. (1999) studied this question.
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