Reaction of an Osmium(VI) Nitrido Complex with Enamines generated in situ from Ketones and Anilines

Lei Wang; Lixing Wang; Zengcheng Liu; Fang Xu; Rui-Yue Qi; Wai‐Lun Man; Jing Xiang; Xueqing Liu; Tai‐Chu Lau

doi:10.1039/d5dt01334h

January 1, 2025Dalton Transactions

Reaction of an Osmium(VI) Nitrido Complex with Enamines generated in situ from Ketones and Anilines

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Key Points

The reaction yields a new osmium complex, demonstrating the versatility of nitrido complexes in organic synthesis.
Complex [OsIII(L)(CN)3(L1)]− is formed from acetone and 2,4,6-trimethylaniline, indicating a significant transformation.
Assessment of the reaction showcases the interaction of osmium with various ligands and substrates effectively.
Further exploration may enable broader applications for osmium complexes in synthetic organic procedures.

Implication

The reaction reveals complex formation from ketones and anilines, suggesting new pathways in organometallic chemistry.

Abstract

The reaction of [OsVI(N)(L)(CN)3]− (OsN, HL = 2-(2-hydroxy-5-nitrophenyl)-benzoxazole) with a mixture of acetone and 2,4,6-trimethylaniline (MesNH2) affords [OsIII(L)(CN)3(L1)]− (L1 = N-mesityl-2-(mesitylimino)propanimidamide), where L1 is derived from the combination of an...

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Cite This Study

Wang et al. (2025) studied this question.

synapsesocial.com/papers/68af4760ad7bf08b1ead46f6 https://doi.org/10.1039/d5dt01334h

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Reaction of an Osmium(VI) Nitrido Complex with Enamines generated in situ from Ketones and Anilines

Key Points

Implication

Abstract

Discussion

Cite This Study

Reaction of an Osmium(VI) Nitrido Complex with Enamines generated in situ from Ketones and Anilines

Key Points

Implication

Abstract

Discussion

Cite This Study

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