January 1, 2025

Reaction of an Osmium(VI) Nitrido Complex with Enamines generated in situ from Ketones and Anilines

Key Points

The reaction yields a new osmium complex, demonstrating the versatility of nitrido complexes in organic synthesis.
Complex [OsIII(L)(CN)3(L1)]− is formed from acetone and 2,4,6-trimethylaniline, indicating a significant transformation.
Assessment of the reaction showcases the interaction of osmium with various ligands and substrates effectively.
Further exploration may enable broader applications for osmium complexes in synthetic organic procedures.

Abstract

The reaction of OsVI(N)(L)(CN)3− (OsN, HL = 2-(2-hydroxy-5-nitrophenyl)-benzoxazole) with a mixture of acetone and 2,4,6-trimethylaniline (MesNH2) affords OsIII(L)(CN)3(L1)− (L1 = N-mesityl-2-(mesitylimino)propanimidamide), where L1 is derived from the combination of an...

Reaction of an Osmium(VI) Nitrido Complex with Enamines generated in situ from Ketones and Anilines

Key Points

Abstract

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