This method demonstrates efficient halo-phosphorothiolation of alkenes with N-phosphorothiosuccinimide, emphasizing its nucleophilic halogen source.
Herein, we developed the electrophilic intermolecular halo-phosphorothiolation of unactivated alkenes with TMSX as an activator and a nucleophilic halogen source.
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Zhang et al. (2025) studied this question.
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