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Synthesis of iron metallomacrocycles demonstrates unique isotherms and adsorption behavior, highlighting potential in gas storage applications.
Three iron metallomacrocycles were synthesized and characterized using single crystal X-ray crystallography. Varying the amide coligand allows for macrocycles containing three, four, or six iron centers. The metallomacrocycles show extended structures in the solid state that are reminiscent of metal-organic framework structures; thus, the adsorbative properties of the complexes in the solid state have been investigated using N2. Based on the data, three metallomacrocyles display classical type II isotherms and pore size distributions synonymous with mesoporous materials.
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Barrett et al. (2025) studied this question.
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