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September 23, 2025Synfacts

Regiodivergent Nickel-Catalyzed Interrupted Chain-Walking of Unsaturated Alcohols

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Key Points

Regiodivergent reactions of unsaturated alcohols were achieved using nickel catalysis, leading to unique products.
The study highlights the importance of using traceless directing groups for facilitating chain-walking processes.
Unique C(sp³)–H functionalization strategies demonstrated innovative pathways in the context of organic synthesis.
The findings suggest potential applications in developing new synthetic methodologies and complex molecular structures.

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Implication

This research demonstrates regiodivergent outcomes of nickel catalysis in alcohols, highlighting the role of traceless directing groups.

Abstract

Keywords chain-walking - nickel catalysis - traceless directing groups - C(sp³)–H functionalization

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Cite This Study

A 2025 study studied this question.

synapsesocial.com/papers/68d4764731b076d99fa6dfb3 https://doi.org/10.1055/a-2680-8978

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