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Heterostructures consisting of PbZr 0.2 Ti 0.8 O 3 epitaxial films on a SrTiO 3 (100) substrate with a La 0.67 Sr 0.33 MnO 3 bottom electrode were prepared by pulsed laser deposition. Plane-parallel capacitor structures were investigated by dielectric spectroscopy and piezoelectric measurement. Shift in a piezoelectric loop indicates that a sample has a small imprinted internal field, directed towards the copper top electrode. Temperature-dependent measurements in a range of 300–500 K were performed to obtain information on the frequency-depending response of the metal–ferroelectric–metal (MFM) structure and to analyze the effect of charge injection through the two Schottky-like contacts. The charge injection process greatly increases the conductivity in the low-frequency region.
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Haronin et al. (2024) studied this question.
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