Observational analysis reveals a transition-metal-free process for trifluoromethyl ketones, implying efficient chemical transformations.
A transition-metal-free deoxygenative functionalization of trifluoromethyl ketones via a Pudovik addition/phospha-Brook rearrangement sequence followed by benzylic substitution has been developed. The reaction proceeds under mild conditions to afford a variety...
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Junichiro Yamaguchi (2025) studied this question.
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