This method employs photoredox and Brønsted acid catalysis to enhance asymmetric synthesis of difluoroalkyl compounds, suggesting improved efficiency.
A catalytic asymmetric difluoroalkylation/rearrangement of alkenylfurans with difluoroalkyl sulfones and anilines has been developed. This method employs cooperative photoredox/Brønsted acid catalysis, enabling efficient and versatile synthesis of difluoroalkyl-containing 4-aminocyclopentenones with excellent diastereo- and enantioselectivities.
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Yang et al. (2025) studied this question.
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