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Involvement of osmium catalysis shows diastereoselective production of oxetanes from 1,4-dienes, suggesting a new pathway in organic synthesis.
In this paper, an osmium catalyzed oxidative cyclization of 1,4-dienes is reported. The reaction undergoes exo ,exo-type cyclization, with oxetanes obtained for the first time as oxidative cyclization products. Catalytic amount...
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Wang et al. (2025) studied this question.
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