Demonstrates the utility of 1,4-diaxial atropisomers in asymmetric catalysis, highlighting new applications.
-chromenediols (BINCOLs) from identical symmetric triol precursors. The 1,4-diaxial BINCOLs demonstrate considerable utility as promising ligands in asymmetric catalysis, as evidenced by the successful application in Cu-catalyzed enantioselective C-H thiolation of ferrocene carboxamide. Furthermore, the 1,4-diaxial BINCOLs exhibit an aggregation-induced emission effect, highlighting their potential as a new class of polycyclic aromatic AIEgens.
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De-zheng et al. (2026) studied this question.
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