Second-harmonic generation in two hybrid organicinorganic metal chlorides based on L-thioproline ligand

Yingjie Wang; Peiqi Qian; Xuemei Wen; Hongmei Zeng; Guohong Zou; Zhien Lin

doi:10.1039/d6ce00330c

January 1, 2026CrystEngComm

Second-harmonic generation in two hybrid organicinorganic metal chlorides based on L-thioproline ligand

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Key Points

This study aims to investigate the second-harmonic generation properties of two hybrid organic-inorganic metal chlorides using L-thioproline as a ligand.
Synthesis of single crystals of (L-C4H8NO2S)CuCl₂ and (L-C4H7NO2S)₂ZnCl₂ using L-thioproline as ligands.
Characterization of the structural properties and optical behavior of the obtained crystals.
Both hybrid metal chlorides exhibit different low-dimensional structures.
Efficient second-harmonic generation was observed in both compounds.

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Implication

Demonstrates second-harmonic generation in hybrid metal chlorides, suggesting new optical materials.

Abstract

Single crystals of (L-C4H8NO2S)CuCl₂ (1) and (L- C4H7NO2S)₂ZnCl₂ (2), were obtained using L-thioproline molecules as terminal ligands. The two hybrid metal chlorides exhibit different low-dimensional structures and efficient second-harmonic generation...

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Wang et al. (2026) studied this question.

synapsesocial.com/papers/6a1a80550307b785094324af https://doi.org/10.1039/d6ce00330c

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Second-harmonic generation in two hybrid organicinorganic metal chlorides based on L-thioproline ligand

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

Second-harmonic generation in two hybrid organicinorganic metal chlorides based on L-thioproline ligand

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

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