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Photocatalyst-free method synthesizes difluoroalkyl-containing coumarins, suggesting a novel approach for organic synthesis.
A photocatalyst-free and electron donor-acceptor (EDA) complexenabled radical difluoroalkylation/cyclization of unactived alkenes with bromodifluoroacetamides has been developed for the efficient synthesis of difluoroalkyl-containing polycyclic coumarin derivatives, affording a total of...
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Yan et al. (2026) studied this question.
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