The title compound has a quasi-trigonal bipyramidal (or alternatively, distorted octahedral) structure with a symmetrically bound acetate ligand and cis-dioxo ligands in the trigonal plane, and is an effective oxidant for halides, alcohols, sulphides, and phosphines, functioning catalytically in the presence of N-methylmorpholine-N-oxide (NMO) as co-oxidant.
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Griffith et al. (1990) studied this question.
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