Ce(III) containing tricobalt-substituted silico-tungstate [CeCo3Si2W20O74(NO3)(OH)(H2O)]13-: A versatile nano-cluster with a multitude of applications

Shivani .; Vivek Das; Ahsan  ul Haq; Shivangi Prandiyal; Anwar Alam; Anne‐Lucie Teillout; Pedro de Oliveira; Arun Kant; Himani Chahar; Debabrata Mishra; Olivier Blacque; Firasat Hussain

doi:10.1039/d6dt00088f

January 1, 2026Dalton Transactions

Ce(III) containing tricobalt-substituted silico-tungstate [CeCo3Si2W20O74(NO3)(OH)(H2O)]13-: A versatile nano-cluster with a multitude of applications

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Key Points

The aim is to explore a new cerium-based tricobalt-substituted silico-tungstate nano-cluster.
Synthesis of CeCo3Si2W20O74(NO3)(OH)(H2O) nano-cluster.
Characterization of structural properties.
Isolation of related structures with early lanthanoids.
Isolated a structurally distinct cerium-containing nano-cluster with potential applications.
Characterization confirmed the Keggin-type framework of the complex.

Implication

This work reports a novel cerium-containing silico-tungstate complex, unveiling its diverse applications.

Abstract

In this work, we report a structurally distinct cerium-containing tricobalt-substituted Keggin-type silico-tungstate [CeCo3Si2W20O74(NO3)(OH)(H2O)] 13-. In addition to the Ce-based complex (2a), we have also isolated structures including other early lanthanoids...

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. et al. (2026) studied this question.

synapsesocial.com/papers/6a250b0e7def13d035e1b15c https://doi.org/10.1039/d6dt00088f

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Ce(III) containing tricobalt-substituted silico-tungstate [CeCo3Si2W20O74(NO3)(OH)(H2O)]13-: A versatile nano-cluster with a multitude of applications

Key Points

Implication

Abstract

Discussion

Cite This Study

Ce(III) containing tricobalt-substituted silico-tungstate [CeCo3Si2W20O74(NO3)(OH)(H2O)]13-: A versatile nano-cluster with a multitude of applications

Key Points

Implication

Abstract

Discussion

Cite This Study

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