Phase Change Materials for Photovoltaic Thermal Management: A Comprehensive Review of Material Innovations and Hybrid Architectures

The escalating global demand for renewable energy has positioned solar photovoltaics (PV) as a critical technology for achieving net-zero emissions. However, PV efficiency is strictly limited by thermal degradation, where elevated operating temperatures significantly reduce power output and accelerate material aging. This review systematically evaluates the integration of advanced phase change materials (PCMs) as a passive thermal management solution. We analyze the transition from material-level innovations—including nano-enhanced PCMs, 3D conductive frameworks, and shape-stabilization—to system-level hybrid architectures such as liquid—PCM, heat pipe-fin, and thermoelectric generator (TEG) integrations. Synthesis of recent empirical data (2024–2026) demonstrates that optimized PCM composites can achieve PV temperature reductions of up to 32 °C and electrical efficiency enhancements exceeding 19%. Furthermore, techno-economic assessments reveal that these systems can reduce the levelized cost of energy (LCOE) by 5–15% and achieve energy payback times as short as 1.5 years. Finally, this paper identifies critical research gaps in long-term outdoor durability, AI-driven predictive modeling, and sustainable bio-based encapsulation, providing a strategic roadmap for the commercialization of next-generation solar thermal management systems.