2-Deoxy sugars are now directly accessible from 1-glycosyl halides: glycosyl radicals generated with Bu3SnH rearrange in accordance with 1 → 2 into the 2-deoxy sugars. Glycosyl dihalides afford the corresponding dideoxy sugars. C⊙ in 1 and 2 denotes C-1 and C-2, respectively, of a carbohydrate.
No takes yet. Share an insight, caveat, or question.
Giese et al. (1987) studied this question.
Synapse has enriched 3 closely related papers on similar clinical questions. Consider them for comparative context: