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Rhodium-catalyzed enantioselective coupling generates homoallylic sulfamates from arylboronic acids and imines, indicating efficiency in reactions.
A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3‐enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl‐to‐allyl 1,4‐rhodium(I) migration.
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Callingham et al. (2017) studied this question.
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