Randomized trial demonstrates divergent functionalizations of α-trifluoromethyl alkenes, suggesting versatile synthetic applications.
-retentive anti-Markovnikov hydroalkoxylation. Switching the reaction atmosphere, photocatalyst, and solvent further diverts the same starting materials to defluorinative esterification and aerobic hydroxylative alkoxylation, providing a divergent synthesis of fluorinated and ester-functionalized structures.
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Li et al. (2026) studied this question.
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