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A facile in situ polymerization was developed for grafting renewable cardanol onto the carbon fiber (CF) surfaces to strengthen the fiber-matrix interface. CFs were chemically modified with hydroxyl groups by using an aryl diazonium reaction, and then copolymerized in situ with hexachlorocyclotriphosphazene (HCCP) and cardanol to build cardanol-modified fibers (CF-cardanol). The cardanol molecules were successfully introduced, as confirmed using Raman spectra and X-ray photoelectron spectroscopy (XPS); the cardanol molecules were found to increase the surface roughness, energy, interfacial wettability, and activity with the matrix resin. As a result, the interlaminar shear strength (ILSS) of CF-cardanol composites increased from 48.2 to 68.13 MPa. In addition, the anti-hydrothermal ageing properties of the modified composites were significantly increased. The reinforcing mechanisms of the fiber-matrix interface were also studied.
Zheng et al. (Sat,) studied this question.