A novel unsymmetrical ditertiary phosphine, Ph2PCH2CH2P(CF3)2, and its chelate complex cis-[PdCl2{Ph2PCH2CH2P(CF3)2}] have been prepared and characterised; the molecular structure of the latter compound shows that the organic substituents on the phosphorus atoms exert a profound effect on the metal–ligand bonding and that the trans-influence of the PPh2 group is considerably greater than that of the P(CF3)2 group.
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Manojlović‐Muir et al. (1974) studied this question.
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