Bis(carboxycyclopentadienyl) cobalt Co(C5H4CO2H)2+(1) and the cobalt(III) sepulchrate Co(sep)3– 9(2) produce hydrogen from water after single elecron reduction in an electrochemical process, and act as electron relays in photochemical hydrogen generating systems.
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Houlding et al. (1982) studied this question.
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